CAS 72287-26-4

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium

Description:

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium, commonly referred to as Pd(dppf)Cl2, is a coordination complex featuring palladium as the central metal atom. This compound is characterized by its bidentate ligand, 1,1′-bis(diphenylphosphino)ferrocene (dppf), which provides two phosphorus donor atoms that coordinate to the palladium center. The structure typically exhibits a square planar geometry around the palladium, which is common for d8 metal complexes. Pd(dppf)Cl2 is notable for its role as a catalyst in various organic reactions, particularly in cross-coupling reactions such as the Suzuki and Stille reactions, due to its ability to facilitate the formation of carbon-carbon bonds. The presence of the ferrocene moiety contributes to the stability and solubility of the complex in organic solvents. Additionally, the dichloride form indicates that it contains two chloride ligands, which can be replaced in catalytic processes. Overall, this compound is valued in synthetic organic chemistry for its effectiveness and versatility as a catalyst.

Formula: C₃₄H₂₈Cl₂FeP₂Pd

InChI: InChI=1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q2*-1;;;2*+2/p-2

InChI key: InChIKey=NXQGGXCHGDYOHB-UHFFFAOYSA-L

SMILES: [Cl-][Pd+2]1([Cl-])[P]([C-]23[Fe+2]456789%10([C-]%11([CH]4=[CH]5[CH]6=[CH]7%11)[P]1(C%12=CC=CC=C%12)C%13=CC=CC=C%13)[CH]2=[CH]8[CH]9=[CH]%103)(C%14=CC=CC=C%14)C%15=CC=CC=C%15

Synonyms:

• (Bis(η⁵-(diphenylphosphino)cyclopentadienyl)iron)dichloropalladium
• (SP-4-2)-[1,1′-Bis(diphenylphosphino-κP)ferrocene]dichloropalladium
• 1,1'-Bis(diphenylphosphino)ferrocenedichloropalladium(II)
• 1,1′-Bis(diphenylphosphino)ferrocenepalladium dichloride
• Dichloro(diphenylphosphinoferrocene)palladium
• Dichloro[1,1′-bis(diphenylphosphine)ferrocene]palladium(II)
• Dichloro[1,1′-bis(diphenylphosphino)ferrocene]palladium
• Dichloro[1,1′-bis(diphenylphosphino)ferrocene]palladium(II)
• Ferrocene, 1,1′-bis(diphenylphosphino)-, palladium complex
• Palladium, [1,1′-bis(diphenylphosphino)ferrocene-P,P′]dichloro-, (SP-4-2)-
• Palladium, [1,1′-bis(diphenylphosphino-κP)ferrocene]dichloro-, (SP-4-2)-
• Pd(dppf)Cl₂
• PdCl₂(dpdf)
• PdCl₂(dppf)
• [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium
• [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
• [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) dichloride
• [1,1′-Bis(diphenylphosphino)ferrocene]dichloro-palladium(II)

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

CAS: 72287-26-4

Formula: C₃₄H₂₈Cl₂FeP₂Pd

Purity: 98%

Color and Shape: Solid

Molecular weight: 731.7046

Ref: IN-DA00360V

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

CAS: 72287-26-4

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

Formula: C₃₄H₂₈FeP₂·Cl₂Pd

Purity: ≥95%

Color and Shape: very dark red solid

Molecular weight: 731.70464g/mol

Ref: 54-OR8775

(1,1''-Bis(diphenylphosphino) ferrocene) dichloropalladium(II)

CAS: 72287-26-4

Formula: C₃₄H₂₈Cl₂FeP₂Pd

Purity: ≥ 98.0%

Color and Shape: Red to dark red or brown crystalline powder

Molecular weight: 731.70

Ref: 7W-GK3496

1,1′-Bis(diphenylphosphino)ferrocenepalladium (II) dichloride

CAS: 72287-26-4

Formula: C₃₄H₂₈Cl₂FeP₂Pd

Purity: 98.0%

Molecular weight: 731.71

Ref: 10-F035791

[1,1'-Bis(diphenylphosphino)ferrocene]-dichloropalladium (II)

Controlled Product

CAS: 72287-26-4

[1,1'-Bis(diphenylphosphino)ferrocene]-dichloropalladium (II) is a catalyst used in cross-coupling reactions. It has been shown to be an efficient catalyst for the synthesis of substituted benzene derivatives. The presence of substituents on the benzene ring influences its reactivity and selectivity with respect to other substrates. In addition, it can be used as a photochemical source of ferrocenium ions, which are useful intermediates in organic synthesis. This compound is also used to simulate the reaction mechanisms of thiophene and triazine compounds.

Formula: C₃₄H₂₈Cl₂FeP₂Pd

Purity: Min. 95%

Color and Shape: Red Powder

Molecular weight: 731.7 g/mol

Ref: 3D-FB13964

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium (II)

Controlled Product

CAS: 72287-26-4

Applications [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds.

Formula: C₁₇H₁₄P·2Cl·Fe·Pd

Color and Shape: Dark Red

Molecular weight: 731.7

Ref: TR-B430465

1,1'-Bis(Diphenylphosphino)Ferrocene Palladium(II) Dichloride extrapure, 14.5% Pd

CAS: 72287-26-4

Formula: (C₁₇H₁₄P)₂Fe·PdCl

Color and Shape: Red to dark red, Crystalline powder

Molecular weight: 731.7

Ref: SR-16660

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

CAS: 72287-26-4

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (PDCL2(DPPF)) is a catalyst.

Formula: C₃₆H₃₄Cl₂FeP₂Pd

Purity: 98%

Color and Shape: Solid

Molecular weight: 761.77

Ref: TM-T60227