CAS 858971-43-4

(SP-4-2)-Bis(acetato-κO)[1,1′-[1,2-ethanediylbis(sulfinyl-κS)]bis[benzene]]palladium

Description:

The chemical substance known as "(SP-4-2)-Bis(acetato-κO)[1,1′-[1,2-ethanediylbis(sulfinyl-κS)]bis[benzene]]palladium" is a palladium complex characterized by its coordination with acetate ligands and a unique bidentate ligand structure involving a sulfinyl group. This compound typically exhibits a square planar geometry, which is common for palladium(II) complexes. The presence of the sulfinyl groups contributes to its potential reactivity and stability, while the acetate ligands can influence solubility and interaction with other molecules. The compound may exhibit interesting catalytic properties, particularly in organic synthesis, due to the palladium center's ability to facilitate various reactions, including cross-coupling reactions. Additionally, the specific arrangement of the ligands can affect the electronic properties and sterics of the complex, making it a subject of interest in coordination chemistry and materials science. Overall, this compound exemplifies the diverse chemistry of transition metal complexes and their applications in catalysis and materials development.

Formula: C₁₄H₁₄O₂S₂·C₄H₆O₄Pd

InChI: InChI=1/C14H16O2S2.2C2H4O2.Pd/c15-17(13-7-3-1-4-8-13)11-12-18(16)14-9-5-2-6-10-14;2*1-2(3)4;/h1-10,17-18H,11-12H2;2*1H3,(H,3,4);/q;;;+2/p-2/rC18H22O6PdS2/c1-15(19)23-25(24-16(2)20)26(21,17-9-5-3-6-10-17)13-14-27(25,22)18-11-7-4-8-12-18/h3-12,26-27H,13-14H2,1-2H3

InChI key: InChIKey=SNNYSJNYZJXIFE-UHFFFAOYSA-L

SMILES: [O-](C(C)=O)[Pd+2]1([O-]C(C)=O)[S](=O)(CC[S]1(=O)C2=CC=CC=C2)C3=CC=CC=C3

Synonyms:

• (SP-4-2)-Bis(acetato-κO)[1,1′-[1,2-ethanediylbis(sulfinyl-κS)]bis[benzene]]palladium
• 1,2-Bis(phenylsulfinyl)ethanepalladium(II)acetate
• Palladium, bis(acetato-κO)[1,1′-[1,2-ethanediylbis(sulfinyl-κS)]bis[benzene]]-, (SP-4-2)-
• White catalyst
• 1,2-Bis(phenylsulfinyl)ethane-palladium diacetate
• 1,2-Bis(phenylsulfinyl)ethane palladium(II) acetate
• 1,2-Bis(phenylsulfinyl)ethanepalladium(II) acetate, min. 98%
• 1,2-Bis(phenylsulfinyl)ethane Palladium(II) Diacetate
• 1,2-Bis(phenylsulfinyl)ethanepalladium(II)acetate,min.98%ChristinaWhiteCatalyst
• 1,2-Bis(phenylsulfinyl)ethanepalladium(II) acetate,Christina White Catalyst,98%
• 1,2-Bis(phenylsulfinyl)ethanepalladiuM(II) acetate,98% Christina White Catalyst

1,2-Bis(phenylsulfinyl)ethane Palladium(II) Diacetate

CAS: 858971-43-4

Formula: C₁₈H₂₀O₆PdS₂

Purity: >96.0%(T)

Color and Shape: Orange to Amber to Dark red powder to crystal

Molecular weight: 502.89

Ref: 3B-B3292

1,2-Bis(phenylsulfinyl)ethanepalladium(II) acetate, min. 98% Christina White Catalyst

CAS: 858971-43-4

1,2-Bis(phenylsulfinyl)ethanepalladium(II) acetate, min. 98% Christina White Catalyst

Formula: C₁₈H₂₀O₆PdS₂

Purity: min. 98%

Color and Shape: orange to brown pwdr.

Molecular weight: 502.90

Ref: 08-46-0245

1,2-BIS(PHENYLSULFINYL)ETHANE-PALLADIUM DIACETATE

CAS: 858971-43-4

Formula: C₁₈H₂₀O₆PdS₂

Purity: 97%

Color and Shape: Solid

Molecular weight: 502.8978

Ref: IN-DA0032KF

1,2-Bis(Phenylsulfinyl)Ethane Palladium(II) Acetate

CAS: 858971-43-4

1,2-Bis(Phenylsulfinyl)Ethane Palladium(II) Acetate

Purity: 97%

Molecular weight: 502.9g/mol

Ref: 54-IN11761

1,2-Bis(phenylsulfinyl)ethane Palladium(II) Diacetate

CAS: 858971-43-4

1,2-Bis(phenylsulfinyl)ethane Palladium(II) Diacetate is an oxidation catalyst that can be used in the production of detergent compositions. It is synthesized by reacting 1,2-bis(phenylsulfinyl)ethane with palladium acetate in aqueous solution at room temperature. The reaction occurs spontaneously and proceeds through a mechanism involving initial hydrolysis to form the mixed sulfonylchloride and subsequent oxidation to give the mixed sulfonyl-palladate salt. The optimal reaction conditions for this reaction are pH 7, 60°C, and 0.5 equivalents of water vapor. FT-IR spectroscopy has been used to identify the particle size of this catalyst as well as confirm its identity. This catalyst can be used for both stereoselective and non-stereoselective reactions due to its high surface area, which leads to increased reactivity. Other catalysts such as

Formula: C₁₈H₂₀O₆PdS₂

Purity: Min. 95%

Molecular weight: 502.9 g/mol

Ref: 3D-FB60973