CymitQuimica logo

CAS 92051-23-5

:

1,3,4,6-tetra-O-acetyl-2-O-triflat-beta-D-mannopyranose

Description:
1,3,4,6-Tetra-O-acetyl-2-O-triflate-β-D-mannopyranose is a derivative of mannose, a six-carbon aldose sugar. This compound features multiple acetyl groups and a triflate group, which enhance its reactivity and solubility in organic solvents. The presence of the acetyl groups indicates that the hydroxyl groups on the sugar have been acetylated, which typically improves stability and alters the compound's physical properties. The triflate group, a strong leaving group, makes this compound particularly useful in organic synthesis, especially in glycosylation reactions. The β-D-mannopyranose configuration suggests that the hydroxyl group at the anomeric carbon is in the equatorial position, which influences the compound's stereochemistry and reactivity. This compound is often utilized in carbohydrate chemistry for the synthesis of more complex oligosaccharides and glycosides. Its unique structural features make it a valuable intermediate in the development of glycosylated compounds for pharmaceutical and biotechnological applications.
Formula:C15H19F3O12S
InChI:InChI=1/C15H19F3O12S/c1-6(19)25-5-10-11(26-7(2)20)12(27-8(3)21)13(14(29-10)28-9(4)22)30-31(23,24)15(16,17)18/h10-14H,5H2,1-4H3/t10-,11-,12+,13+,14-/m1/s1
InChI key:OIBDVHSTOUGZTJ-PEBLQZBPSA-N
SMILES:CC(=O)OC[C@@H]1[C@H]([C@@H]([C@@H]([C@@H](O1)OC(=O)C)OS(=O)(=O)C(F)(F)F)OC(=O)C)OC(=O)C
Synonyms:
  • tetra-O-acetyl-2-O-trifluoromethane-sulfonyl-beta
  • beta-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate
  • Mannose Triflate
  • 1,3,4,6-tetra-O-acetyl-2-O-trifluoro-methanesulfonyl
  • -beta-D-mannopyranose
  • Tatm
  • 1,3,4,6-tetra-O-acetyl-2-O-[(trifluoromethyl)sulfonyl]hexopyranose
  • 1,3,4,6-tetra-O-acetyl-2-O-[(trifluoromethyl)sulfonyl]-beta-D-mannopyranose
  • 1,3,4,6-tetra-O-acetyl-2-O-trifluoro-methanesulfonyl
  • -beta-D-mannopyranose
Found 9 products.