CAS 94594-90-8

(2R)-Bornane-10,2-sultam

Formula: C₁₀H₁₇NO₂S

InChI: InChI=1/C10H17NO2S/c1-9(2)7-3-4-10(9)6-14(12,13)11-8(10)5-7/h7-8,11H,3-6H2,1-2H3/t7-,8-,10+/m0/s1

Synonyms:

• [3aS-(3aalpha,6alpha,7abeta)]-Hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-dioxide
• (1S)-(-)-2,10,Camphor sultam
• 8,8-Dimethyloctahydro-4,7-Methano-2,1-Benzothiazole 2,2-Dioxide
• (7aR)-8,8-dimethylhexahydro-3a,6-methano-2,1-benzothiazole 2,2-dioxide
• (3aS,6R,7aR)-8,8-dimethylhexahydro-3a,6-methano-2,1-benzothiazole 2,2-dioxide
• (6R)-8,8-dimethylhexahydro-3a,6-methano-2,1-benzisothiazole 2,2-dioxide
• (3aS,6S,7aS)-8,8-dimethylhexahydro-3a,6-methano-2,1-benzisothiazole 2,2-dioxide
• (-)-Camphorsultam
• (1S)-(-)-2,10-Camphorsultam
• (1S)-(-)-2,11-Camphorsultam

(-)-10,2-Camphorsultam

CAS: 94594-90-8

Formula: C₁₀H₁₇NO₂S

Purity: >98.0%(GC)

Color and Shape: White to Almost white powder to crystal

Molecular weight: 215.31

Ref: 3B-C1325

(1S,2R)-(-)-10,2-Camphorsultam, 99%

CAS: 94594-90-8

(1S,2R)-(-)-10,2-Camphorsultam is used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl--methylcysteine. It is used as proton source in the synthesis of chiral ,-substituted -butyrolactones. It is also employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographi

Formula: C₁₀H₁₇NO₂S

Purity: 99%

Color and Shape: Crystals or powder or crystalline powder, White to pale cream

Molecular weight: 215.31

Ref: 02-A15897

(3aS,6R,7aR)-8,8-Dimethylhexahydro-1H-3a,6-methanobenzo[c]isothiazole 2,2-dioxide

CAS: 94594-90-8

Formula: C₁₀H₁₇NO₂S

Purity: 98%

Color and Shape: Solid

Molecular weight: 215.3125

Ref: IN-DA003BJT

(1S)-(-)-2,10-Camphorsultam

CAS: 94594-90-8

(3aS,6R,7aR)-8,8-Dimethylhexahydro-1H-3a,6-methanobenzo[c]isothiazole 2,2-dioxide

Formula: C₁₀H₁₇NO₂S

Purity: 99%

Molecular weight: 215.31

Ref: IN-DG01517884

(1S,5R)-10,10-Dimethyl-3-Thia-4-Azatricyclo[5.2.1.0(1,5)]Decane 3,3-Dioxide

CAS: 94594-90-8

(1S,5R)-10,10-Dimethyl-3-Thia-4-Azatricyclo[5.2.1.0(1,5)]Decane 3,3-Dioxide

Formula: C₁₀H₁₇NO₂S

Purity: 97%

Molecular weight: 215.31

Ref: 54-OR1007931

(-)-10,2-Camphorsultam

CAS: 94594-90-8

Formula: C₁₀H₁₇NO₂S

Molecular weight: 215.32

Ref: 7W-GK5124

(1S)-(-)-2,10-Camphorsultam

CAS: 94594-90-8

Formula: C₁₀H₁₇NO₂S

Purity: 98%

Color and Shape: Crystalline

Molecular weight: 215.31

Ref: 10-F078916

(1S)-Camphorsultam

Controlled Product

CAS: 94594-90-8

Applications (1S)-Camphorsultam is used as a chiral auxiliary to control the stereochemistry in order to obtain the desired stereoselective product. It’s also a reagent used to make Camphorsultam conjugates, and used as a catalyst with the help of a lewis acid in organic reactions such as the Diels-​Alder reaction, and the Grignard reaction.
References Springthorpe, B., et al.: Bioorg. Med. Chem. Lett., 17, 6013 (2007); Inoue, M., et al.: Nat. Chem., 2, 280 (2010); Chapuis, C., et al.: Pol. J. Chem., 68, 2323-31 (1994); Merhcan, F.L., et al.: Tetrahedron: Asymmetry, 7, 667-70 (1996);

Formula: C₁₀H₁₇NO₂S

Color and Shape: Neat

Molecular weight: 215.13

Ref: TR-C175125