Cyano-, Nitrile-

Applications Methyl 4-Cyanobenzoate (cas# 1129-35-7) is a compound useful in organic synthesis.

Applications 4-Biphenylacetonitrile is a useful synthetic intermediate. It was used to study the adsorption orientation of the biphenyl derivatives on the Au colloidal surfaces with α-cyclodextrins. 4-Biphenylacetonitrile on condensation reaction with ethyl phenyl propiolate yields biphenyl derivatives of acetylenic β-ketocyanide.
References Lee, J., et al.: Bull. Korean. Chem. Soc., 30, 1637 (2009); Al-Jallo, H., et al.: J. Chem. Eng. Data, 17, 513, (1972)

Applications p-Cyanobenzoic Acid Trimer is used in the synthetic preparation of Terbium Triazinetribenzoate Formate Metal Organic Framework (MOF).
References Han, Y., et al.: J. Mater. Chem. A Mater. Energy Sustain., 3, 24525 (2015)

Applications 6-cyano-2-oxaspiro[3.3]heptane-6-carboxylic acid (cas# 1934971-05-7) is a useful research chemical.

Applications 3-Cyanobenzoic Acid, is a building block used for the synthesis of a variety of 3,5-disubstituted 1,2,4-oxadiazoles from carboxylic acids, that can be used for the synthesis of a metabotropic glutamate subtype 5 (mGlu5) receptor antagonist.
References Ramu, T., et al.: Chem. Lett., 42, 722 (2013);

Applications Tert-butyl 3-amino-4-cyanobenzoate is a useful compound for organic synthesis.

Applications Tetrakis(acetonitrile)palladium Bis(tetrafluoroborate) is used to prepare an α-Diimine-transition metal complex, which is used as a catalyst for polymerization of olefins. It is also a catalyst used in cross coupling reaction for C-C, C-O, and C-N bond formation.
References Feldman, J., et al.: Organometallics, 16, 1514 (1997); Johnson, L., et al.: PCT Int. Appl., WO 9623010 A2 19960801 (1996); Poppenbery, J., et al.: Surface Sci., 2011; Pijnenburg, N., et al.: Dalton Transactions, 40, 8896 (2011); Kilpin, K., et al.: Inorg. Chem., 50, 6334 (2011)

Applications 4-CYANO-4-[(ETHYLSULFANYLTHIOCARBONYL)SULFANYL]PENTANOIC ACID (cas# 1137725-46-2) is a useful research chemical.

Applications 4-cyano-N,N-dimethylbenzamide (cas# 24167-50-8) is a useful research chemical.

Applications 4-Cyanocyclohexanone is used to prepare nicotinamides as PDE4 D isoenzymes inhibitors. It is also used as an anthranilic acid replacement in niacin receptor agonist.
References Marfat, A., et al.: PCT Int. Appl. (1998), WO 9845268 A1 19981015; Schmidt, D., et al.: Bioorg. Med. Chem. lett., 20, 3426 (2010)

Applications N-​(4-Cyanophenyl)​-6-​benzothiazolecarboxa​mide is a compound used in the synthesis of piperazines presenting neuro and psychotropic agent with low toxicity.

2-Cyanophenothiazine is an aliphatic hydrocarbon that belongs to the class of industrial chemicals. It is used as a reactant in organic synthesis, such as for the production of 2-cyanophenols and 2-phenylbenzimidazole. This compound can be produced by reacting n-hexane with amide or n-dimethylformamide. 2-Cyanophenothiazine has been shown to have mitochondrial biogenesis effects and increase mitochondrial membrane potential in thp-1 cells. It also has biological properties, such as being anti-inflammatory and having antitumor activity.

Ethyl (Ethoxymethylene) cyanoacetate is a chemical compound that belongs to the family of aldehyde compounds. It is a colorless liquid at room temperature, with an odor similar to that of acetic acid. The compound has been used in the synthesis of epidermal growth factor and diazonium salts. It has also been used in the production of anti-cancer drugs such as malonic acid, which inhibits tumor growth by inhibiting protein synthesis. Ethyl (Ethoxymethylene) cyanoacetate reacts with quinoline derivatives to form carbon disulphide, which can be used as an antimicrobial agent and insecticide.

4-Fluoro-3-nitrophenylacetonitrile is a monomer that can be synthesised from the reaction of carbamic acid and diphenyl ether. It is chiral, stereoselective and nucleophilic. 4-Fluoro-3-nitrophenylacetonitrile can also be synthesised by reacting fluoroacetamide with sodium cyanide in water, forming the corresponding amide, which reacts with acetonitrile to form the nitro compound. The anti-cancer properties of 4-fluoro-3 nitrophenylacetonitrile have been studied in vitro and in vivo. This substance has been shown to inhibit growth of cancer cells and induce apoptosis. In addition, this substance has been used as a synthetic strategy for dihydroisoquinolines, which are important for their anti-cancer properties.

Potassium tetracyanoaurate(III) (K[AuCl4]) is a crystalline, intermetallic compound that has been used in the production of coatings, spherical particles, and electrochemical materials. The pentahydrate form has a diameter of 4.8-5.2 Å and a melting point of ~115°C. K[AuCl4] is stable in air and water but reacts with strong acids to form potassium chloride and potassium tetracyanocuprate(II). This substance also has an optimal pH range of 6-7 and an average solubility range of 0.05-0.1g/100mL at 20°C. The microstructure of K[AuCl4] is not well understood because it is difficult to isolate from other compounds during synthesis.

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(1-Methyl-1H-benzoimidazol-2-yl)-acetonitrile is a nucleophilic compound that reacts with carbanions to form alkyl benzoates. It can also act as an electrophile in the formation of nitroalkenes and amides, as well as an intermediate in the synthesis of phenazines. The potassium salt of this compound is used as a reagent in organic synthesis. (1-Methyl-1H-benzoimidazol-2-yl)-acetonitrile has been shown to react with methylene and aromatize to produce ethyl cyanoacetate, which can be used for the production of malononitrile. This reaction is catalyzed by potassium carbonate and esters.

Potassium dicyanoargenate is an organic acid that is a precursor to silver nanoparticles. This compound is typically used in the production of cellulose derivatives, and for the activation of polymerization reactions. Potassium dicyanoargenate can also be used to produce insoluble polymers and cationic surfactants by combining it with a metal ion, such as sodium carbonate or hydroxyl groups.

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4-Cyano-2-fluorobenzyl bromide is a methyl ester that can be used as a reagent for the synthesis of chiral α-amino acids. It can also be used as an enantioselective methylating agent for the synthesis of γ-secretase inhibitors. The methodology for the convergent synthesis of this compound includes alkylation with glycine followed by an enantioselective hydrolysis, which results in optically pure 4-cyano-2-fluorobenzyl bromide.

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2-fluoro-4-iodobenzonitrile is a potent inhibitor of the functions of VEGFR receptors. It inhibits the proliferation and migration of cancer cells by binding to VEGFR receptors, which are tyrosine kinases that regulate cell growth and differentiation. 2-Fluoro-4-iodobenzonitrile has been shown to inhibit angiogenesis, or the formation of new blood vessels, in vitro. This drug also has potent inhibitory activity against tumor growth in vivo. Clinical trials have shown that 2-fluoro-4-iodobenzonitrile can be used to treat various types of cancers, including breast cancer and colon cancer.

4-(Dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidinium) (DCJTB) is a red fluorescent dye that emits light when activated by heat. DCJTB is cationic and can be polymerized thermally or chemically. The molecule has been shown to be activated by the addition of an electron donor such as a metal chelate. This reaction takes place in the solution phase. DCJTB has been used for the diagnosis of nonpolar solvents such as gasoline and oil leaks in machine parts. DCJTB has also been used to detect groundwater contamination with trichloroethylene (TCE).