Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%

CAS: 12112-67-3

Ref. 02-012749

Product Information

• Name: Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%
• Synonyms: diiridium(1+) bis(1,5-cyclooctadiene, (Z,Z)-) dichloride, (1,5-Cyclooctadiene)chloroiridium dimer, (1,5-Cyclooctadiene)iridium chloride dimer, (η4-1,5-Cyclooctadiene)iridium chloride dimer, (η⁴-1,5-Cyclooctadiene)iridium chloride dimer, 1,5-Cyclooctadiene, iridium complex, 1,5-cyclooctadiene, chloride, (1Z,5Z)-, diiridium salt, 5-Chlorobis(1,5-cyclooctadiene)diiridium, Bis((μ-chloro)(1,5-cyclooctadiene)iridium), Bis(1,5-cyclooctadiene)diiridium(I) dichloride, Bis(chloro(1,5-cyclooctadiene)iridium), Bis(chloro(cyclooctadiene)iridium), Bis(μ-chloro)bis(1,5-cyclooctadiene)diiridium, Bis[μ-chloro(η⁴-1,5-cyclooctadiene)iridium], Chloro(1,5-cyclooctadiene)iridium dimer, Chloro(cyclooctadiene)iridium dimer, Cyclooctadieneiridium chloride dimer, Di-Μ-Chlorobis[(1,2,5,6-Η)Cycloocta-1,5-Diene]Diiridium, Di-Μ-Clorobis[(1,2,5,6-Η)Cicloocta-1,5-Dien]Diiridio, Di-μ-Chlorobis(1,5-cyclooctadiene)diiridium, Di-μ-Chlorobis(π-1,5-cyclooctadiene)diiridium, Di-μ-chlorobis(η4-1,5-cyclooctadiene)diiridium, Di-μ-chlorobis(η4-1,5-cyclooctadiene)diiridium(I), Di-μ-chlorobis(η⁴-1,5-cyclooctadiene)diiridium, Di-μ-chlorobis(η⁴-1,5-cyclooctadiene)diiridium(I), Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium, Di-μ-chlorobis[(1,2,5,6-η)cycloocta-1,5-dien]diiridium, Di-μ-chlorobis[(1,5-cyclooctadiene)iridium], Di-μ2-chlorobis(1,5-cyclooctadiene)diiridium, Di-μ₂-chlorobis(1,5-cyclooctadiene)diiridium, Dichlorobis(1,5-cyclooctadiene)diiridium, Dichlorobis(cyclooctadiene)diiridium, Dichlorobis(η4-1,5-cyclooctadiene)diiridium, Dichlorobis(η⁴-1,5-cyclooctadiene)diiridium, Iridium, di-μ-chlorobis(1,5-cyclooctadiene)di-, Iridium, di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]di-, Iridium, dichlorobis(cyclooctadiene)di-, Nsc 326162, μ,μ-Dichlorobis(1,5-cyclooctadiene)diiridium

Description

Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Brand: Alfa Aesar By Thermo Fisher Scientific

Chemical properties

• Molecular weight: 671.70
• Formula: C₁₆H₂₄Cl₂Ir₂
• InChI key: ZFOUDQNHNLDNLD-MIXQCLKLSA-L