1,6-Anhydro-β-D-glucopyranose

CAS: 498-07-7

Ref. TR-A648100

Product Information

• Name: 1,6-Anhydro-β-D-glucopyranose
• Synonyms: (1R,2S,3S,4R,5R)-6,8-dioxabicyclo[3.2.1]octane-2,3,4-triol, 1,6-Anhydro-<span class="text-smallcaps">D</span>-glucopyranoside, 1,6-Anhydro-<span class="text-smallcaps">D</span>-glucose, 1,6-Anhydro-Beta-D-Glucopyranose, 1,6-Anhydro-D-glucopyranoside, 1,6-Anhydro-D-glucose, 1,6-Anhydro-β-<span class="text-smallcaps">D</span>-glucopyranose, 1,6-Anhydro-β-<span class="text-smallcaps">D</span>-glucose, 1,6-Anhydroglucose, 1,6-anhidro-β-D-glucosa, 6,8-Dioxabicyclo[3.2.1]octane, β-<span class="text-smallcaps">D</span>-glucopyranose deriv., <span class="text-smallcaps">D</span>-Glucose, 1,6-anhydro-, D-Glucose, 1,6-anhydro-, GLUCOPYRANOSE (,beta.-D), 1,6-ANHYDRO-, Leucoglucosan, Levoglucosan, Nsc 46243, β-<span class="text-smallcaps">D</span>-Glucopyranose, 1,6-anhydro-, β-D-Glucopyranose, 1,6-anhydro-

Description

Stability Hygroscopic
Applications 1,6-Anhydrohexopyranoses have proven to be valuable synthons for the preparation of biologically important and structurally diverse products (e.g. rifamycin S, indanomycin, thromboxane B2, (+)-biotin, tetrodotoxin, quinone, and macrolide antibiotics) as well as for modified sugars.The chemical/physical/toxicological properties have not been thoroughly investigated. Since it is known to be a minor component of certain food materials it may be regarded as of relatively low toxicity.
References Fraser-Reid, B., et al. J. Am. Chem. Soc. 106, 731 (1984); Edwards, M.P., et al. J. Org. Chem. 49, 3503 (1984); Kelly, A.G., and Roberts, J.S. J. Chem. Soc., Chem. Commun. 228, (1980); Ogawa, T., et al. Carbohydr. Res. 57, C31 (1977); Isobe, M., et al. Tetrahedron Lett. 28, 6485 (1987); Fresnos, J.N. and Swenton, J.S. , J. Chem. Soc., Chem. Commun. 658, (1985); Kochetkov, N.K. et al., Tetrahedron Lett. 22, 4315, 4319 (1981); Georges, M. et al., Carbohydr. Res. 130, 115 (1984); Paulsen, et al., Chem. Ber. 114, 322 (1981).

• Brand: TRC

Chemical properties

• Molecular weight: 162.14
• Formula: C₆H₁₀O₅
• Color/Form: Neat
• InChI: InChI=1S/C6H10O5/c7-3-2-1-10-6(11-2)5(9)4(3)8/h2-9H,1H2/t2-,3-,4+,5-,6-/m1/s1
• InChI key: InChIKey=TWNIBLMWSKIRAT-XKOXVXMFSA-N
• SMILES: O[C@@H]1C2CO[C@H](O2)[C@H](O)[C@H]1O