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2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine
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2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine

CAS: 145100-51-2

Ref. TR-B585565

1g
92.00 €
5g
142.00 €
10g
228.00 €
Estimated delivery in United States, on Friday 14 Feb 2025

Product Information

Name:
2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine
Controlled Product
Synonyms:
  • N-(5-Chloro-2-pyridinyl)-1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide
  • Comins' Reagent
  • N,N-Bis(trifluoromethylsulfonyl)-5-chloro-2-pyridinamine
  • N,N-Bis(trifluoromethylsulfonyl)-5-chloro-2-pyridylamine
  • N-(5-Chloro-2-pyridyl)triflimide
  • N-(5-Chloropyridin-2-yl)-1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide
  • NSC 683533
  • 1-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine
  • 2-[N,N-Bis(Trifluoromethanesulfonyl)Amino]-5-Chloropyridine
  • 2-[N,N-Bis(Trifluoromethylsulphonyl)amino]-5-chloropyridine
  • See more synonyms
  • 2-[N,N-Bis(trifluoromethanesulphonyl)amino]-5-chloropyridine
  • Bistrifluoromethylsulfonylaminochloropyridine
  • Comins
  • Comins' reagent
  • Methanesulfonamide, N-(5-chloro-2-pyridinyl)-1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-
  • N-(5-Chloro-2-pyridyl)-N-(trifluoromethanesulfonyl)trifluoromethanesulfonamide
  • N-(5-Chloro-2-pyridyl)bis(trifluoromethanesulfonimide)
  • N-(5-chloropyridin-2-yl)-1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide
Description:

Stability Moisture Sensitive, Unstable in DMSO Solution
Applications 2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine also known as Comins’ Reagent is used as a triflyl compouind in the synthesis of vinyl triflates from metallo enolates.
References Comins, D., et al.: Tetrahedron Lett., 33, 6299 (1992);

Notice:
Our products are intended for lab use only. For any other use, please contact us.
Brand:
TRC
Long term storage:
Notes:

Chemical properties

Molecular weight:
392.68
Formula:
C7H3ClF6N2O4S2
Color/Form:
Neat
InChI:
InChI=1S/C7H3ClF6N2O4S2/c8-4-1-2-5(15-3-4)16(21(17,18)6(9,10)11)22(19,20)7(12,13)14/h1-3H
InChI key:
InChIKey=TUFGVZMNGTYAQD-UHFFFAOYSA-N
SMILES:
O=S(=O)(N(c1ccc(Cl)cn1)S(=O)(=O)C(F)(F)F)C(F)(F)F
MDL:
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Hazard Info

UN Number:
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Forbidden to fly:
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