9-Mesityl-10-methylacridinium Tetrafluoroborate

CAS: 1442433-71-7

Ref. TR-M258620

Product Information

• Name: 9-Mesityl-10-methylacridinium Tetrafluoroborate
• Synonyms: 10-Methyl-9-(2,4,6-trimethylphenyl)-acridinium Tetrafluoroborate(1-) (1:1)
• Brand: TRC

Description

Stability Hygroscopic
Applications 9-Mesityl-10-methylacridinium Tetrafluoroborate can be used for the synthesis of γ-butyrolactones, γ-lactams and pyrrolidines. 9-Mesityl-10-methylacridinium Tetrafluoroborate has been reported by Nicewicz et al. to mediate myriad transformations through Photoredox Catalysis. The applications include the anti-Markovnikov hydroamination of alkenes and addition of carboxylic acids to alkenes and the hydrotrifluoromethylation of styrenes using the Langlois reagent S673690.
References Gesmundo, N. J. et al.: Org. Lett. 17, 1316 (2015); Zeller, M. A., et al.: Org. Lett. 16, 4810 (2014); Nicewicz et al., J. Am. Chem. Soc., 135 (26), 9588–9591(2013)

Chemical properties

• Molecular weight: 399.23
• Formula: C₂₃H₂₂BF₄N
• Color/Form: Neat
• InChI: InChI=1S/C23H22N.BF4/c1-15-13-16(2)22(17(3)14-15)23-18-9-5-7-11-20(18)24(4)21-12-8-6-10-19(21)23;2-1(3,4)5/h5-14H,1-4H3;/q+1;-1
• SMILES: Cc1cc(C)c(-c2c3ccccc3[n+](C)c3ccccc23)c(C)c1.FB(F)F.[F-]