Organoboranes

Applications TETRAMETHYLAMMONIUM BOROHYDRIDE (cas# 16883-45-7) is a useful research chemical.

Stability Moisture Sensitive
Applications n-Octadecyltrichlorosilane (cas# 112-04-9) is a useful research chemical.
E0

Stability Light and Temperature sensitive
Applications PFPA-silane is a functionalized perfluorophenyl azides for covalent immobilization of ultrathin polymer films.
References Mosbach, K., et al.: Biotechnology, 14, 163 (1996), Keren, K., et al.: Science, 297, 72 (2002), Lidstrom, M., et al.: Nature Rev. Microbiol., 1, 158 (2003),

Applications 1-Butenylboronic Acid is a reagent used in the synthesis of polyene natural products.
References Lee, S. J., et al.: J. Am. Chem. Soc., 130, 466-468 (2008)

Stability Volatile
Applications Allyltrimethylsilane is used in the allylation of aldehydes, imines, allylic and benzylic alcohols, and chiral α-keto-amides that are derived from (S)-proline esters.
Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package
References Yadav, J.S., et al.: Tetrahedron Lett., 43, 3783 (2002); Aggarwal, V.K., et al.: Tetrahedron Lett., 37, 3745 (1996); Wang, D.K., et al.: J. Org. Chem., 64, 4233 (1999); Kaur, G., et al.: Tetrahedron Lett., 38, 2521 (1997); Soai, K., et al.: J. Chem. Soc., Chem. Commun., 15, 1016 (1984)

Stability Air Sensitive, Moisture Sensitive
Applications It is used for synthesis of unsymmetrical biaryls via aromatic C-H borylation-cross-coupling sequence.
References Stephens, T. et al.: Org. Lett., 19, 3498 (2017);

Applications 3,4-Dihydro-2H-1,4-benzoxazine-7-boronic acid pinacol ester is a useful intermediate for the synthesis of naphthamides which functions as VEGFR-2 kinase inhibitors for cancer treatment.
References Lv, Y., et al.: ACS Med. Chem. Lett., 5, 592 (2014)

Applications Isopropenylboronic Acid Pinacol Ester, can be used as an intermediate in the synthesis of variety of cyclic and acyclic organic compounds. It is also shown that the α-Substituted Allyl/Croty of this compound can be used for highly Diastereo- and Enantioselective allylboration of aldehydes.
References Salaun, J. et al.: Topics in Curr. Chem. 1, 144 (1988); Chen, J. et al.: J. Amer. Chem. Soci., 135, 5316 (2013);

Applications 2-Carboxyfuran-5-boronic acid, pinacol ester

Applications 2-Aminobenzeneboronic acid pinacol ester is a reagent used to synthesize regiospecific quinolines. It can also be used to synthesize (±)-Epimeloscine and (±)-Meloscine.
References Zhang, H., et al.: J. Am. Chem. Soc. 133, 10376 (2011); Horn, J., et al.: Org. Lett 10, 4117 (2008)

Applications 1,3-Dihydro-1-hydroxy-2,1-benzoxaborol-5-ol is used as a reagent in the synthesis of P4-benzoxaborole-substituted macrocyclic inhibitors of HCV NS3 protease.
References Ding, C.Z., et al.: Bioorg. Med. Chem. Lett., 20, 7317 (2010)

Applications 2-Cyclohexylvinylboronic Acid is used in the synthesis of vinylbenziodoxolones, a novel type of hypervalent iodine(III) reagents.
References Stridfeldt, E., et al.: Chem. Eur. J., 22, 16066-16070 (2016)

Applications 5-Formylfuran-2-boronic Acid Pinacol Ester could be useful for the diastereoselective synthesis of cyclic peptide macrocycles via Petasis borono-Mannich reaction
References Yamaguchi, A., et al.: Chem. Commun. (Cambridge, U. K.), 55, 10567 (2019)